Novel Caulks

专利摘要:
A composite caulk comprising paper wool, perlite, a particulated wood material having a particle size below 2 mm, a particulated fire retardant bark material having at least one axis of length with a dimension below 2 mm and a polyvinyl-acetate based aqueous dispersion adhesive; and wherein said composite caulk forms a heterogeneous caulk which can be dispensed using a handheld caulking gun
公开号:DK201400749A1
申请号:DKP201400749
申请日:2014-12-23
公开日:2016-07-04
发明作者:Curt Andersen
申请人:Papiruld Danmark As；
IPC主号:

专利说明:

TITLE
Novel Caulks FIELD
The present invention relates to caulks for caulking e.g. windows and other building objects installed into the outer walls of buildings, wherein it is desirable to create a water resistant seal between building object and wall, which is at the same time easy to apply, water resistant yet does not discolor due to fungicidal growth.
BACKGROUND
It is a persistent problem in building construction that materials and construction elements of a variety of constituent materials must be joined together to form the building. Windows of glass must, be fitted into frames of metal, wood or plastics, window frames must be fitted into the sustaining walls, which are typically made from concrete or bracks; and the walls must be secured to the buildings foundation in order for the building to remain standing. In particular in modern buildings, construction elements very often arrive prefabricated at the building site and are inserted into the building's frame work with minimal or no adaptation of the prefabricated c o n s t r u c t i ο n e1ement.
In many cases, such as a window frame being fitted into a brick or a concrete construction, the construction element arrives prefabricated with a dimension which is smaller by a significant margin (often dictated by governmental standards), leaving a gap between the prefabricated construction element and the building-proper. While this is advantageous as it eases the insertion of the prefabricated construction element into the building and minimizes any subsequent adaptation, the joints between the element and the burlding proper must necessarily be closed prior to human use of the finished building.
The process of closing such joints between building elements is known as caulking and the materials used are considered caulks. The function of caulking is to provide thermal insulation, control water penetration and noise mitigation ,
Historically, caulks were either mortar or plasto-elastrc materials such as e.g. pitch. Today a variety of caulks are known. In particular plasto-elastic materials, known as sealants, are ubiquitously used in the building industry. In this respect, plasto-elastic materials have the advantage over mortar that they are easy to apply, normally using a handheld caulking gun, and will retain a fluid-tight joint seal over many years all the while permitting the different construction materials the freedom to become displaced relative to each other with the varying weather conditions experienced by the building during the lifetime of the sealant.
Numerous construction chemicals are sold as caulk such as e.g. silicone, and acrylic sealants. Unlike construction caulk, which is applied where no building movement is expected, a sealant is made of elastomeric materials that typically allow movement of 25% to 50% of the width of the joint. Silicone sealants form a durable, water-tight seal, but are not typically paintable. Some silicone sealants are made to be paintable with certain types of paint such as water or oil-based paints. Other sealants are paintable.
Sealants are commonly sold in cartridges which are loaded into a pistol-like caulking- gun (opening at the side) or barrel gun (opening at the end) for application. During the tool-working time, which varies by chemistry, the caulk can be pressed into the joint so that it can bond with the materials on both sides, and also be smoothed. The time it takes for a chemical sealant to become a rubber is known as the curing time and varies by temperature and humidity. It is an advantage of modern sealants that they bond well to the various surfaces encountered in modern building construction materials.
A problem of modern plasto-elastic sealant materials when used as caulks compared to mortar is the leakage of plasticizers over time, which reduces the strength of the seal and can lead to costly and time consuming recaulking of the j oint. Another problem compared to mortar of modern plasto-elastic sealant materials when used as caulks is the low diffusivity of the sealant material for w a t Θ r .
In a building, water is ubiquitously present both indoors as well as outdoors. Trapping water inside a building will lead to significant problems with mold growth and an associated and very significant health risk to the individuals living inside the building. Permitting the water to leave the building by venting the building or by actively removing moisture using air condition systems is therefore necessary. However, at cold spots or next to water impermeable surfaces, water will accumulate and molding may occur.
This problem is particularly persistent where modern sealants are applied as caulks as these are not diffusion open to via ter. Such sealants are therefore often attacked by molds leading to unaesthetically looking joints while potentially posing health risks. Further, the vapor barrier created by the water tight seal will be at the wrong (indoor) side of the building. This may cause wooden window frames or wallpaper next to the joint to mold, which can be costly in repairs and poses a potential health risk. Hence it is an object of the present invention to suggest improved caulks which at least partially will overcome the problem of molding· of the joint during the joint's life time.
Another aesthetic problem of modern sealants compared to mortar is related to the color of the seal. Modern sealants generally do not have an aesthetically pleasing color compared to the buildings surface, often differing significantly from the colors of the other building materials. It is therefore another aspect of the present invention to suggest improved caulks which at least partially will overcome this problem and wherein the improved caulks of the invention have a color and an appearance traditionally associated with mortar, yet retaining the ease of applicability and good adhesive properties associated with modern sealants.
A further problem of modern sealants is their relative high cost per volume. This repeatedly creates the need for filling the intermediate volume between the building objects with cheaper filling material, typically an insulating material, prior to application of the sealant. This adds an additional handling step in the construction process, requiring additional man power and man time, which is an unnecessary added cost. Accordingly, there is further the need for a caulk which is insulating yet less expensive compared to modern sealants.
To these purposes the present inventors suggest the use of a composite caulk comprising paper wool, perlite, a particulated wood material having- a particle size below 2 mm, a particulated fire retardant bark material having at least one axis of length with a dimension below 2 mm and a p o 1 y v i n y 1 - a c e t a t e b a s e d a qu e o u s d i s pe r s i ο n a dh e s i v e; and wherein the composite caulk forms a heterogeneous caulk which can be dispensed using a handheld caulking gun .
In the art, US 3,468,414 it is known to make instant paper mache which comprises perlite as a mechanical binder or filler for enhancing the porosity of the paper mache following its ultimate usage and drying. The compositions of US 3,468,414 contains in percentage by weight: Paper (80% newspaper, 20% magazine) 45.7-47.2%, a r t o r mo1di n g p1aster 16.6-17.2 %, per1i t e 9.7-17.1 %, borated dextrin 5.6-7.9%, salt 4.3-6.6%, starch 4.3-11.1%, and carboxy methyl cellulose 4.2-5.7%; and were found suitable for making simple preformed building elements, such as e.g. bricks. However, the prior art is silent on the composite caulks of the present art as well as their intended use.
SUMMARY OF THE INVENTION
In a first aspect and embodiment of the present invention there is disclosed a composite caulk comprising paper wool, perlite, a particulated wood material having a particle size below 2 mm, a particulated fire retardant bark material having at least one axis of length with a dimension below 2 mm and a polyvinyl-acetate based aqueous dispersion adhesive; and wherein said composite caulk forms a heterogeneous caulk which can be dispensed using a handheld caulking gun.
In a second embodiment of said first aspect there is disclosed a composite caulk further comprising- an aqueous modified starch dispersion adhesive or an aqueous modified starch dispersion adhesive reinforced with an aqueous acrylic dispersion.
In a third embodiment of said first, aspect, there is disclosed a composite caulk according to either said first aspect or said second embodiment wherein the fire retardant bark material is cork.
In a fourth embodiment of said first aspect there is disclosed a composite caulk, according to any of said a b o v e me n t i ο n e d e mb o d i m e n t s w h e r e i n t h e po 1 y v i n. y 1 - a. cetate based aqueous dispersion adhesive is a water resistant adhesive in class D3 of DIK EN 204.
In a fifth embodiment of said first aspect there is disclosed a composite caulk according to any of said abovementzoned embodiments comprising on a weight/weight b a s i. s ;
Paper wool : 3 --- 10 %;
Perlite : 10 - 20 %;
Particulated Wood : 15 --- 25 %;
Particulated Bark : 10-20 %; T h e b a 1 a n c e a dh e s i ve .
In a sixth embodiment of said first aspect there is disclosed a composite caulk according to any of said abovementioned embodiments comprising on a weight/weight basis :
Paper wool : 4 - 7 %;
Perlite : 11 - 16 %;
Particulated Wood : 17 - 23 %;
Particulated Bark : 13 - 18 %;
The balance adhesive.
In a seventh embodiment of said first aspect there is disclosed a composite caulk according either said fifth or said sixth embodiment; wherein said aqueous modified starch dispersion adhesive or said aqueous modified starch dispersion adhesive reinforced with an aqueous acrylic dispersion constitutes up to 10% of the total mass of adhesive.
In an eighth embodiment of said first, aspect, there is disclosed a composite caulk according to any of said abovementioned embodiments further comprising biologically at least one fungicide in an amount efficient to retard or hinder growth of fungus in said composite eau1k.
In a second aspect of the present invention there is disclosed a method of making a composite caulk comprising paper wool, perlite, a particulated wood material having a particle size below 2 mm, a particulated fire retardant bark material having at least one axis of length with a dimension below 2 mm and a polyvinyl-acetate based aqueous dispersion adhesive; and wherein the composite caulk forms a heterogeneous caulk which can be dispensed using a handheld caulking gun; wherein paper wool, perlite, particulated wood and particulated bark are dry mixed prior to mixing with said adhesive (is); wherein when present said at least, one fungicide is mixed into said composite caulk with or after addition of said adhesive (s); wherein when present said aqueous modified starch dispersion adhesive or said aqueous modified starch dispersion adhesive reinforced with an aqueous acrylic dispersion is added after; said polyvinyl-acetate based aqueous dispersion adhesive and wherein said adhesive or adhesives is/are added in an amount sufficient to obtain a heterogeneous caulk which can be dispensed using- a handheld caulking gun.
In a third aspect there is disclosed the use of a composite caulk according to any of embodiments of sard first aspect for caulking a joint or a gap between s eparate bu i 1 di ng obj e ct. s inabu i 1 di ng.
DETAILED DESCRIPTION
According to the present invention, there is suggested novel caulks comprising paper wool, perlite, a particulated wood material having a particle size below 2 mm, a particulated fire retardant bark material having at least one axis of length with a dimension below 2 mm and a polyvinyl-acetate based aqueous dispersion adhesive; and wherein the composite caulk forms a heterogeneous caulk which can be dispensed using a handheld caulking gun; and the use such caulks for caulking joints between building objects during building construction or during building maintenance .
Paper wool, or as it is also known cellulose insulation, consists of about 85% cellulosic materials, typically recycled newspaper, and about 15% of fire retardant minerals such as e.g. boric acid, ammonium sulfate or aluminum hydroxide. In the experimental compositions of the present invention the paper wool consisted of 87.5% recycled newspaper, 8.7% aluminum hydroxide, 0.9% borax and 2.9% boric acid. While paper wool having a composition as described above is preferably used in the composite caulks of the invention, the exact composition of the comprised paper wool is not considered limiting on t n e i n v e n t i ο n .
The use of paper wool in the composite caulks of the present invention serves several purposes. Paper wool enhances the caulk matrix, is fire retarding as well as insulating and further provides a color palette which allows the composite caulks of the present invention to approach that of mortar.
Paper wool is present in the composite caulks of the present invention in an amount based on weight/total weight of between 3 to 10%, more preferably between 4 to 7%, and most preferably around 5%.
Perlite is used for enhancing the porosity of the caulk as is known in the art as well as for structural stability of the hardened caulk. In addition thereto, the addition of a mineral component enhances the visual aspect and the desired visual mortar-like appearance of the enhanced caulks.
Perlite is present in the composite caulks of the present invention in an amount based on weight/total weight of between 10 to 20%, more preferably between 11 to 16%, and most preferably around 14%.
Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It has been used for thousands of years for both fuel and as a construction material. It is an organic material, a natural composite of cellulose fibers (which are strong-in tension) embedded in a matrix of lignin which resists compression. In the context of the present disclosure, wood ('while sometimes defined as only the secondary xylem in the stems of trees) is defined more broadly to include the same type of tissue elsewhere such as in the roots of trees or shrubs. The present invention utilizes wood as a composite filler to add tensional strength and resilience a g a i n s t c o mp r e s s i ο n.
In the context of the present disclosure there is used particulated wood having a particle size below 2 mm. One way of obtaining such particulated wood material could be by using sawdust, which is a cheap and abundant surplus material from the wood and carpentry industries. The skilled person will understand that some fraction of the particulated wood material can be larger than 2 mm without influencing the quality and flow properties of both the fresh as well as the hardened caulk. However, m order to achieve a suitable heterogeneous caulk which can be dispensed using a handheld caulking gun, it is important that the fraction of oversized particles is kept to a minimum. Particles smaller than 1 mm influence the caulk very little, however it is preferable that the majority of wood particles have sizes in the range of 1 mm to 2 mm in order to maximize the influence of the particufated wood on the structural properties of the hardened caulk.
No particular limitation is placed on the source of wood used in the present invention. Likewise, two or more sources of wood may be present in the composite caulks of the invention without influencing the final product. It has been found that in order to optimize the composite caulk, wood from so-called softwood (such as elder wood) is less preferable, while wood from so-called medium hardness wood (such as pinewood, birch, beech) or hardwood (such as oak, teak) are more suitable. Particulated. wood which is naturally fire retardant is preferred.
Particulated wood is present in the composite caulks of the present: invention in an amount based on weight/total weight of between 15 to 25%, more preferably between 17 to 23%, and most preferably around 20%.
Bark is the outermost layers of stems and roots of woody plants. Plants with bark include trees, woody vines, and shrubs. Bark refers to all the tissues outside of the vascular cambium and is a nontechnical term. It overlays the wood and consists of the inner bark and the outer bark. The inner bark, which in older stems is living tissue, includes the innermost area of the periderm. The outer bark in older stems includes the dead tissue on the surface of the stems, along with parts of the innermost periderm and all the tissues on the outer side of the periderm. The outer bark on trees is also called the rhytidome.
In the context of the present disclosure there is used a particulated fire retardant bark material having at least one axis of length with a dimension below 2 mm. One way of obtaining such particulated fire retardant bark material could be by using sawdust, which is a cheap and abundant surplus material from the wood and carpentry industries. The skilled person will understand that some fraction of the particulated fire retardant bark material can be larger than 2 mm without influencing the quality and flow properties of both the fresh as well as the hardened caulk. However, in order to achieve a suitable heterogeneous caulk which can be dispensed using a hand held caulking gun, it is important that the fraction of oversized particles is kept to a minimum. Particles smaller than 1 mm influence the caulk very little, however it is preferable that the majority of particulated fire retardant bark particles nave sizes in the range of 1 mm to 2 mm m order to maximize the influence of the particulated fire retardant bark on the structural properties of the hardened caulk.
One very suitable bark material in relation to the present invention is cork, Cork is an impermeable, buoyant material, a prime-subset of bark tissue that is harvested for commercial use primarily from Quercus sober (the Cork Oak), which is endemic to southwest Europe and northwest Africa. Cork is composed of suberin, a hydrophobic substance, and because of its impermeable, buoyant, elastic, and fire retardant properties, it is used in a variety of products, the most common of which is for wine stoppers. However, other sources of fire retardant bark exit and are equally suitable for use in the context of the present invention. Nevertheless, cork 1 S Q y p τ 0 y τ£ o
Particulated fire retardant bark is present in the composite caulks of the present invention in an amount based on weight/total 'weight of between 10 to 20%, more preferably between 13 to 18%, and most preferably around 15% .
The composite caulk comprising paper wool, perlite, a particulated wood material having a particle size below 2 mm, a particulated fire retardant bark material having at least one axis of length with a dimension below 2 mm further comprises a polyvinyl-acetate based aqueous dispersion adhesive.
The aqueous dispersion adhesive constitutes the matrix of the composite caulk and hence constitutes the sealing-material of the caulk. Aqueous polyvinyl“acetate dispersions are known to form good adhesives for porous stone, e.g. such as bricks or concrete, and further-advantageous in the improved caulks of the present invention as cross-linking and curing of the adhesive is enhanced by the presence of boric acid in the paper wool. The aqueous dispersions suitable for the present invention have a dry matter content of from 40 to 50% by weight of the dispersion, most preferably between 44 to 46% dry matter.
It is preferable, that the polyvinyl-acetate based aqueous dispersion adhesives suitable for the present invention have a water resistance durability class below D2 according· to DIN EN 2 04 as in place at the filing date of the present application. Preferably, the durability class of the adhesive is not below D3 according to DIN EN 204, and most preferably, the adhesive is classifiable as a D3 adhesive according to DIN EN 204, A suitable example of a commercially available adhesive is ProFect© 2343 from PKI Industrilim of Fredericia, Denmark.
It is further advantageous, but not required to modify and adjust the flow properties of the composite caulk using aqueous modified starch dispersion adhesives or aqueous modified starch dispersion adhesives reinforced with an aqueous acrylic dispersion. Such adhesives are well known as wall paper adhesives and form a good connecting matrix between the paper, wood, and bark components of the composite caulk and the inorganic components of both the composite caulk of the invention as well as the building objects where-be tween the caulk is applied.
If present, the aqueous modified starch dispersion adhesives or aqueous modified starch dispersion adhesives reinforced with an aqueous acrylic dispersion are present in an amount up to 10% of the total mass of adhesive, preferably up to 5% of the total mass of the adhesive. Suitable aqueous modified starch dispersion adhesives or aqueous modified starch dispersion adhesives reinforced with an aqueous acrylic dispersion in general have between 15 and 25% by weight of the aqueous modified starch dispersion adhesive dry matter, most preferably about 20% by weight of dry matter. A suitable example of a commercially available adhesive is DANA LIM vådrumslim 216 from Dana Lim of Køge, Denmark.
Adhesive is present in balancing amounts sufficient to reach 10 0% by weight when the weight percentage sum of the dry matter components is compiled.
While in general cured polyvinyl-acrylates have a good resistance to fungi, it can in circumstances be advantageous to further include at least one fungicide in an amount biologically efficient to retard or hinder growth of fungus in the composite caulks of the invention. Such fungicides are preferentially added to the adhesives prior to mixing with the dry matter components in the composite caulks of the invention. Suitably, commercially available adhesives comprising premixed adhesive and fungicide can be used for ease of m a n u f a c t u r i n g.
It is further required that the composite caulk forms a heterogeneous caulk which can be dispensed using a handheld caulking gun.
Handheld caulking guns are well-known in the art. They permit a person so desiring to dispense a viscous liquid, composition or complex fluid from a container, wherein the viscous liquid is contained, and onto a surface. The container usually has a moveable bottom and usually an oppositely positioned opening in the container. During use the caulking gun exerts a pressure through a piston action on the moveable bottom of the container, which causes a displacement of the bottom and of the viscous liquid in the container, causing the viscous liquid to leave the container as long as the piston action is maintained on the bottom.
Such caulking guns are used on viscous liquids of a broad viscosity range. Usually,, the viscosity of the liquid is determined by the liquid's intended use and is not limited by the construction of the caulking guns. In the context of the present invention, the requirement that the composite caulk of the invention shall form a heterogeneous caulk which can be dispensed using a handheld caulking gun shall therefore be understood broadly as being a composite caulk which requires the use of a handheld caulking gun for dispensing, and therefore that the handheld caulking gun must be compressible by a person of normal strength, yet not being so liquid that upon application into a joint or gap in a building, the composite caulk of the invention will lack the necessary viscosity to remain in place in the joint during hardening, i.e. cease being a caulk.
Below are given several examples which will allow the skilled person to manufacture composite caulks according to the invention. The skilled person will understand that the composite caulks of the present invention comprise a significant portion of an aqueous phase from the adhesive. During curing and hardening of the applied caulk, this water evaporates and the final, hardened caulk will therefore have a weight distribution different from the composite caulks described in the below examples , EXAMPLE 1: A composite caulk according to the present invention comprising on a weight/weight basis:
Paper wool : 3 - 10 %;
Perlite : 10 - 20 %;
Particulated Wood : 15 - 25 %;
Particulated Bark : 10 --- 2 0 %; T he b a 1 a n c e a dhe s i ve , EXAMPLE 2: A composite caulk according to the present invention comprising on a weight/weight basis:
Paper wool : 4 - 7 %;
Perlite : 11 - 16 %;
Part,i culated Wood : 17 --- 2 3 %;
Particulated Bark : 13 --- 18 %; ϊ h e b a 1 a n c e a dh e s i ve , EXAMPLE 3:
The composition of either Example 1 or example 2 c o mpr i s i ng an aque ou s mo di f i e d s t a rch di spersi ο n adhesives or aqueous modified starch dispersion adhesives reinforced with an aqueous acrylic dispersion in an amount of 10% of the total mass of adhesive.
EXAMPLE 4:
The composition of either Example 1 or Example 2 comprising an aqueous modified starch dispersion adhesives or aqueous modified starch dispersion adhesives reinforced with an aqueous acrylic dispersion in an amount of 5% of the total mass of adhesive.
According to the invention there is also disclosed a method of making a composite caulk comprising paper wool, perlite, a particulated wood material having a particle size below 2 mm, a particulated fire retardant bark material having at least one ax .is of length with a dimension below 2 mm. and a polyvinyl-acetate based aqueous dispersion adhesive; and wherein the composite caulk forms a heterogeneous caulk which can be dispensed using a handheld caulking gun; wherein paper wool, perlite, particulated wood and particulated bark are dry mixed prior to mixing with said adhesive (s); wherein when present said at least one fungicide is mixed into said composite caulk with or after addition of said adhesive (s); wherein when present said aqueous modif ied starch dispersion adhesive or said aqueous modified starch dispersion adhesive reinforced with an aqueous acrylic dispersion is added after said polyvinyl-acetate based aqueous dispersion adhesive and wherein said adhesive or adhesives is/are added in an amount sufficient to obtain a heterogeneous caulk which can be dispensed using a handheld caulking gun.
Further, there is disclosed the use of a composite caulk according- to any of the embodiments of the invention for-caulking a joint or a gap between separate building objects in a building.
CLOSING COMMENTS
The term "comprising" as used in the claims does not exclude other elements or steps. The term "a" or "an" as used in the claims does not exclude a plurality. A single processor or other unit may fulfill the functions of several means recited in the claims.
Although the present invention has been described in detail for purpose of illustration, it is understood that such detail is solely for that purpose, and variations can be made therein by those skilled in the art without departing from the scope of the invention.

权利要求:
Claims (10)
[1] 1. A composite caulk comprising paper wool, perlite, a particulated wood material having a particle size below 2 mm, a particulated fire retardant bark material having at least one axis of length with a dimension below 2 mm and a polyvinyl-acetate based aqueous dispersion adhesive; and wherein said composite caulk forms a heterogeneous caulk which can be dispensed using a handheld caulking gun.
[2] 2. The composite caulk according to claim 1 further comprising an aqueous modified starch dispersion adhesive or an aqueous modified starch dispersion adhesive reinforced with an aqueous acrylic dispersion .
[3] 3. A composite caulk according to claim 1 or 2 wherein the fire retardant bark material is cork.
[4] 4. A composite caulk according to any of the claims 1 to 3 wherein the polyvinyl-acetate based aqueous dispersion adhesive is a water resistant adhesive in class D3 of DIN EN 204.
[5] 5. A composite caulk according to any of the claims 1 to 4 comprising on a weight/weight basis: Paper wool : 3 - 10 %; Perlite : 10 - 20 %; Particulated Wood : 15 - 25 %; Particulated Bark : 10 - 20 %; T h e b a 1 a n c e a d h e s i v e .
[6] 6. A composite caulk according to any of the claims 1 to 5 comprising on a weight/weight basis: Paper wool : 4 --- 7 %; Perlite : 11-16 %; P a r t i c u 1 a t e d Vi o o d : 17 - 2 3 % ; Particulated Bark : 13 - 18 %; The balance adhesive.
[7] 7. A composite caulk according to either claim 5 or 6; wherein said aqueous modified starch dispersion adhesive or said aqueous modified starch dispersion adhesive reinforced with an aqueous acrylic dispersion constitutes up to 10% of the total mass of adhesive.
[8] 8. A composite caulk according to any of the claims 1 to 7; further comprising biologically at least one fungicide in an amount efficient to retard or hinder growth of fungus in said composite caulk.
[9] 9. A method of making a composite caulk comprising paper wool, perlite, a particulated wood material having a particle size below 2 mm, a particulated fire retardant bark material having at least one axis of length with a dimension below 2 mm and a p o1yvi ny1-acetate base d aque ou s di spe r s i ο n adhesive; and wherein the composite caulk forms a heterogeneous caulk which can be dispensed using a handheld caulking gun; wherein paper wool, perlite, particulated wood and particulated bark are dry mixed prior to mixing with said adhesive (s); wherein when present said at least one fungicide is mixed into said composite caulk with or after addition of said adhesive(s); wherein when present said aqueous modified starch dispersion adhesive or said aqueous modified starch dispersion adhesive reinforced with an aqueous acrylic dispersion is added after said polyvinyl-acetate based aqueous dispersion adhesive and wherein said adhesive or adhesives is/are added in an amount sufficient to obtain a heterogeneous caulk which can be dispensed using a handheld caulking gun.
[10] 10. Use of a composite caulk according to any of the claims 1 to 8 for caulking a joint or a gap between separate building objects in a building.

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US7108744B2|2003-09-15|2006-09-19|Hercules Incorporated|Tape joint compounds with CMC thickener system|

---

US7276551B2|2004-04-06|2007-10-02|Jean-Roch Pageau|Cement composition|

---

DE102004032694A1|2004-07-06|2006-02-02|Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.|Swellable material composition and its use|

---

DE202008003235U1|2008-03-07|2008-06-05|Btf Produktentwicklungs- Und Vertriebs-Gmbh|Aqueous putty, especially for internal insulation|

---

FI20095827A|2009-08-07|2011-02-08|Ekovilla Oy|Wood fiber based insulation and process for making them|

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EP2457972A1|2010-11-30|2012-05-30|Van Loon Chemical Innovations B.V.|New sealant composition|

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法律状态:

优先权:

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申请号 | 申请日 | 专利标题

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DKPA201400749A|DK178740B1|2014-12-23|2014-12-23|Hitherto unknown sealants|DKPA201400749A| DK178740B1|2014-12-23|2014-12-23|Hitherto unknown sealants|

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DK15871998.9T| DK3237570T3|2014-12-23|2015-12-23|Sealant compositions based on polyvinyl acetate and cellulose insulation|

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PCT/DK2015/050415| WO2016101962A1|2014-12-23|2015-12-23|Novel caulks|

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EP15871998.9A| EP3237570B1|2014-12-23|2015-12-23|Caulk compositions based on polyvinyl acetate and cellulose insulation|

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US15/537,775| US10465095B2|2014-12-23|2015-12-23|Caulks|